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Significant Breakthrough in the Key Technology of High-Value Utilization of Olefin Low-Carbon

Time:2021-11-21 Reading:6108

    Under the backdrop of the “Dual Carbon” goals, exploring and developing the high-value utilization of carbon-containing resources is one of the essential approaches for China in building a green, low-carbon, and circular development system and promoting the transformation and upgrading of traditional industries.

 

    The olefin hydroformylation reaction is a process that converts olefins and synthesis gas (CO/H2) into high added-value aldehyde compounds. The produced aldehydes can be further transformed into alcohols, amines, carboxylic acids, and other essential chemical raw materials and fine chemicals. The world's annual production of aldehydes and their derivatives obtained through hydroformylation reactions has exceeded ten million tons, holding substantial economic value. Hence, olefin hydroformylation technology is one of the crucial common technologies in the high-end utilization of carbon resources. In recent years, the large-scale development of modern coal chemical industries like coal-to-oil and coal-to-olefins in China has provided abundant α-olefin raw materials for carbonyl synthesis of high carbon aldehydes. However, due to the high boiling points and poor solubility of high-carbon olefins, several challenges, such as difficult product separation, easy loss of catalysts, low reaction efficiency, and high recovery energy consumption, are encountered in the hydroformylation catalysis process. Consequently, the industrial technology of high-carbon olefin hydroformylation has long been monopolized by foreign entities.

 

    Recently, a breakthrough has been achieved in the key technology for the high-value utilization of high-carbon olefin resources, accomplished collaboratively by our platform and the Shanghai Advanced Research Institute of the Chinese Academy of Sciences. A series of patented technologies, focusing on efficient catalysts and continuous reaction processes, have been developed. These technologies effectively solve problems such as difficulty in catalyst separation and slow reaction rates in the hydroformylation reaction process of high-carbon olefins, achieving continuous and stable operations and the initial completion of technology package compilations. Moving forward, collaborations with relevant enterprises will be established for thousand-ton-level pilot verifications, thus actualizing the industrial demonstration and application of this technology, contributing to the high-end utilization of China's carbon resources.

    This achievement is the result of a collaboration between the Shanghai Low-Carbon Technology Innovation Functional Platform and research institutes. They have fully leveraged their technical abilities in technology development, concept verification, and engineering. This collaboration has enabled the rapid engineering of laboratory results, clearing a fast track for innovative technologies to transition from the laboratory to industrial application. This passage emphasizes the collective effort and the proficient application of technical abilities that facilitated the quick transformation of lab results into practical, industrial applications.

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